Pore shape determination in mesoporous ordered silica films

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Pore shape and sorption behaviour in mesoporous ordered silica films1

Mesoporous silica films templated by pluronic P123 were prepared using spin and dip coating. The ordered cylindrical structure within the films deforms due to shrinkage during calcination. Grazing-incidence small-angle X-ray scattering (GISAXS) measurements reveal that both the unit cell and the cross section of the pores decrease in size, mainly normal to the surface of the substrate, leading ...

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Pore lattice deformation in ordered mesoporous silica studied by in situ small-angle X-ray diffraction

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To use mesoporous silicas as low-k materials, the pore entrances must be really small to avoid diffusion of metals that can increase the dielectric constant of the low-k dielectric. In this paper we present a new method to narrow the pores of mesoporous materials through grafting of a cyclic-bridged organosilane precursor. As mesoporous material, the well-studied MCM-41 powder was selected to a...

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pore-expanded mesoporous silica nanoparticles for PET

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Reversible replication between ordered mesoporous silica and mesoporous carbon.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section A Foundations and Advances

سال: 2016

ISSN: 2053-2733

DOI: 10.1107/s2053273316098971